The Concept of an Element

Our world and universe are made up of millions of different substances. We have already seen how these substances can be classified into solids, liquids and gases. However, on close examination, we find that these substances are made up of a number of small elements.




An element can be defined as a substance that cannot, by any known chemical process, be split into two or more simpler substances. This means that elements cannot, by any chemical process, be made to yield substances simpler than themselves. An element is a substance because it has the same composition throughout.


In 1803, a scientist called John Dalton suggested that each element was made up of its own kind of particles. He called these particles the „atoms‟. Therefore, an element is a substance that is made up of only one kind of atoms.


Names and Symbols of Elements

A chemical symbol is the way of representing an element using initial letter(s). There are many different elements as you have seen above. Every element has a name and a symbol to represent it. Some symbols are just a single capital letter, such as H. Others have two letters, the first of which is always a capital, such as Mg.


Rules for assigning chemical symbols to elements

1. Each element is given a different symbol to represent it.

2. Some elements are represented by two letters e.g. Ca (for calcium), Cl (for chlorine), etc.

3. If two letters represent the element, the first letter is always a capital and the second letter is always a small letter e.g. argon (Ar) and helium (He).

4. In order to avoid confusion, some elements have their chemical symbols derived from Latin names


All symbols are recognized and are used by all scientists all over the world. Some examples of elements and their symbols are given in the table below:

Names and Symbols of some Elements

Element

Symbol

Element

Symbol

 

 

 

 

Aluminium

Al

Bromine

Br

 

 

 

 

Copper

Cu

Carbon

C

 

 

 

 

Iron

Fe

Chlorine

Cl

 

 

 

 

Lead

Pb

Hydrogen

H

 

 

 

 

Magnesium

Mg

Nitrogen

N

 

 

 

 

Mercury

Hg

Oxygen

O

 

 

 

 






Potassium

K

Phosphorus

P

 

 

 

 

Silver

Ag

Sulphur

S

 

 

 

 

Sodium

Na

Silicon

Si

 

 

 

 

Calcium

Ca

Iodine

I

 

 

 

 

Manganese

Mn

Fluorine

F

 

 

 

 

Tin

Sn

Gold

Au

 

 

 

 

Chromium

Cr

 

 

 

 

 

 

Zinc

Zn

 

 

 

 

 

 

Nickel

Ni

 

 

 

 

 

 



It is easy to remember that the symbol for aluminium is Al, and for carbon is C. But some symbols are harder to remember because they are taken from Latin names. For example, potassium has the symbol, K from its Latin name Kalium. Sodium has the symbol, Na from its Latin name Natrium.

See the complete list in the following table. Elements with Latin names.

English name

Latin name

Chemical symbol

 

 

 

Sodium

Natrium

Na

 

 

 

Gold

Aurum

Au

 

 

 

Potassium

Kalium

K

 

 

 

Mercury

Hydrargyrum

Hg

 

 

 

Silver

Argentum

Ag

 

 

 

Antimony

Stibium

Sb

 

 

 






Lead

Plumbum

Pb

 

 

 

Tin

Stannum

Sn

 

 

 

Iron

Ferrum

Fe

 

 

 

Copper

Cuprum

Cu

 

 

 

Tungsten

Wolfram

W

 

 

 


The reason for assigning some elements with Latin names was to avoid confusion among scientists when representing different elements. For example, the symbol for silicon is Si. It could be impossible to represent silicon by the symbol S and at the same time represent the element sulphur by the very symbol, S. 

Similarly, potassium could not be represented by the symbol P that was assigned to phosphorus. So in order to avoid such confusion, scientists decided to use Latin names to represent some elements. In so doing, the anticipated and unnecessary contradiction among scientists from different parts of the world was avoided.

Symbols are particularly useful when more than one atom is present in a substance. For example, hydrogen gas consists of pairs of hydrogen atoms joined together. So hydrogen gas is shown as H2. When more than one atom is joined together like this, we call the substance formed a molecule. 

Atoms making up gases such as hydrogen, oxygen, nitrogen, etc, always exist as molecules. Sulphur exists as a hexagonal ring of eight atoms. Phosphorus exists as a tetrahedron of four atoms. Table below shows some elements that exist as molecules.

Elements that exist as molecules

Element

Atomic symbol

Molecular symbol

 

 

 

Oxygen

O

 

 

 

 

Nitrogen

N

 

 

 

 

Hydrogen

H

 

 

 

 

Sulphur

S

 

 

 

 





Phosphorus

P

 

 

 

 

Chlorine

Cl

 

 

 

 

Fluorine

F

 

 

 

 

Bromine

Br

 

 

 

 

Iodine

I

 

 

 

 


Classification of Elements

Elements can be classified as either metals or non-metals. Metals and non-metals have different physical and chemical properties. This is the criterion used for classification of these elements into metals on one hand and nonmetals on the other hand. Table below summarizes the physical and chemical properties of some common elements.

Properties of some common elements

 

 

 

 

 

 

 

 

 

 

Date

of

Metal or non-

Solid, liquid

Melting

Boiling

Density (

g

Element

discovery

 

metal?

or gas?

point (°C)

point (°C)

cm-3 )

 

 

 

 

 

 

 

 

 

 

Oxygen

1774

 

Non-metal

Gas

-219

-183

0.00132

 

 

 

 

 

 

 

 

 

 

Nitrogen

1772

 

Non-metal

Gas

-210

-196

0.00117

 

 

 

 

 

 

 

 

 

 

Carbon

Ancient

 

Non-metal

Solid

3500

4827

22

 

 

 

 

 

 

 

 

 

 

Iron

1735

 

Metal

Solid

1540

3000

7.9

 

 

 

 

 

 

 

 

 

 

Copper

Ancient

 

Metal

Solid

1080

2500

9.0

 

 

 

 

 

 

 

 

 

 

Lead

Ancient

 

Metal

Solid

327

1744

113

 

 

 

 

 

 

 

 

 

 

Gold

Ancient

 

Metal

Solid

1060

2700

193

 

 

 

 

 

 

 

 

 

 

Silver

Ancient

 

Metal

Solid

961

2200

10.5

 

 

 

 

 

 

 

 

 

 





Hydrogen

1766

Non-metal

Gas

-259

-253

0.00008

 

 

 

 

 

 

 

Aluminium

1825

Metal

Solid

660

2450

27

 

 

 

 

 

 

 

Zinc

1746

Metal

Solid

419

910

7.1

 

 

 

 

 

 

 

Mercury

Ancient

Metal

Liquid

-39

357

13.6

 

 

 

 

 

 

 

Iodine

1811

Non-metal

Gas

114

183

4.9

 

 

 

 

 

 

 

Chlorine

1774

Non-metal

Gas

-101

-35

0.003

 

 

 

 

 

 

 

Sodium

1807

Metal

Solid

98

890

0.97

 

 

 

 

 

 

 

Potassium

1807

Metal

Solid

64

760

0.86

 

 

 

 

 

 

 

Sulphur

Ancient

Non-metal

Solid

119

444

2.1

 

 

 

 

 

 

 

Phosphorus

1669

Non-metal

Solid

44

280

1.8

 

 

 

 

 

 

 


Metals and non-metals

There are 94 naturally occurring elements. Some of them are very rare. Francium, for instance, has never been seen. The radioactive metals neptunium and plutonium, which we make artificially in quite large amounts, only occur in very small (trace) quantities naturally. 

Most of the elements can be classified as metals. The rest are non-metals. To understand these elements better, refer to the Periodic Table of Elements at the back of this book. Classification of elements into metals and non-metals is based on differences between their physical and chemical properties.

Differences between metals and nonmetals are shown in table below.



Mixtures

Compounds

 

 


    A. Physical properties




1. The components of a mixture can be separated

 

 

by  physical  means,  e.g.  filtering,  magnetic

The components of a compound can be separated by chemical means

separation, decantation, etc

only

 

 

 

 

 

2.

 The  composition  of  a  mixture  can  vary

Compounds  are  fixed  in  their  compositions  by  mass  of  elements

widely, e.g. a mixture of 20g of sand with 1g of

present, e.g. there are always 2 atoms of hydrogen to 1 atom of oxygen

salt or vice versa.

in a molecule of water

 

 

 

 

3.

 Mixing  is  not  usually  accompanied  by

 

 

external effects such as explosion, evolution of

Chemical combination is usually accompanied by one or more of these

heat, or volume change (for gases)

effects

 

 

 

 

 

4.

 Properties of a mixture are the sum of the

The properties of a compound are quite different from those of its

properties of the individual constituents of the

constituent  elements.  For  example,  water  is  a  liquid  whereas  its

mixture.

constituent elements, hydrogen and oxygen, are both gases.

 

 

 

5. No new substance is produced as the mixture

 

 

forms

A new substance is always produced when a compound forms.

 

 

 


B. Chemical Properties

 

 


 

 

1.

Give basic oxides, that is, oxides which react with acids

Give acidic oxides, that is, oxides which react with bases

 

 

 

 

2.

Replace hydrogen in acids to form salts

 

Do not react with acids in this manner

 

 

 

 

3.

Form positive (+) ions

 

Form negative (-) ions

 

 

 

4.

Form electrovalent chlorides which are stable in water

Form covalent chlorides which react with water.

 

 

 

 

5.

Do not react with hydrogen

 

Form stable compound with hydrogen

 

 

 

 




There are over 105 different elements known. Of these, 90 have been obtained from the Earth's crust and the atmosphere, and 15 have been artificially made by scientists. From this small band of elements, all other substances on earth are made. 


Elements from Other Substances


Table shows the approximate percentage composition by mass of the elements in the earth's crust, the oceans, and the atmosphere. Can you notice the abundance of oxygen? Analysis of the earth's crust, the oceans, and the atmosphere, reveals that oxygen is the most abundant element on earth, accounting for half the total mass.

Percentage by mass of elements in the earth's crust, oceans and atmosphere

Percentage by mass of elements in the

Percentage by mass of elements in

Percentage by mass of elements in th

earth’s crust

 

the oceans

 

atmosphere

 

 

 

 

 

 

 

Oxygen

47

Oxygen

86

Nitrogen

75.5

 

 

 

 

 

 

Silicon

28

Nitrogen

10.9

Oxygen

23

 

 

 

 

 

 

Aluminium

7.8

Chlorine

1.8

Argon

1.4

 

 

 

 

 

 

Iron

4.5

Sodium

1.0

Hydrogen

0.02

 

 

 

 

 

 

Calcium

3.5

Magnesium

0.1

Carbon

0.01

 

 

 

 

 

 

Sodium

2.5

Calcium

0.05

Others( total)

0.07

 

 

 

 

 

 

Potassium

2.5

Sulphur

0.05

 

 

 

 

 

 

 

 

Magnesium

2.0

Potassium

0.04

 

 

 

 

 

 

 

 

Titanium

0.5

Nitrogen

0.02

 

 

 

 

 

 

 

 

Hydrogen

0.2

Bromine

0.01

 

 

 

 

 

 

 

 

Carbon

0.2

Carbon

0.01

 

 

 

 

 

 

 

 

Others( total)

1.3

Others (total)

0.02